Wen-Yih Ng, Zheng-Yi Choong, Mohamed Faisal Gasim, Fitri Khoerunnisa, Kun-Yi Andrew Lin, Wen-Da Oh
The outbreak of COVID-19 has led to the increase in face mask waste globally. In this study, face mask-derived carbocatalysts doped with nitrogen (N-Mask) were fabricated through one-step pyrolysis of 1:5 w/w mixture of face mask and urea at different temperatures to activate peroxymonosulfate (PMS) for gatifloxacin (GAT) degradation. The N-Mask prepared at 800 °C (N-Mask800) exhibited the highest GAT degradation rate with kapp = 0.093 min−1 which could be attributed to its high N doping level (17.1 wt%) and highest specific surface area (237.13 m2 g−1). The relationship between kapp, catalyst loading and PMS dosage at various pHs on GAT degradation were successfully established. It was also found that the GAT degradation rate was inhibited in the sequential operating mode compared to the simultaneous operating mode. It was construed that adsorption and catalysis share the same active sites. Deterioration in catalytic performance was observed over successive cycles due to the surface chemistry change during catalysis, and difficulty in catalyst recovery after treatment. Radical scavenger study revealed that both radical and nonradical pathways were involved during GAT degradation, with nonradical pathway playing a dominant role. XPS analysis revealed that pyrrolic N and graphitic N can facilitate PMS activation via radical and nonradical pathways. Based on the LC-MS/MS analysis, the GAT degradation intermediates were identified, and the possible degradation pathways were tentatively proposed. Overall, this study demonstrated that carbocatalyst derived from face mask could be transformed into cost-effective and environmentally friendly PMS activator for environmental wastewater treatment applications. © 2022
School of Chemical Sciences, Universiti Sains Malaysia, Penang, 11800, Malaysia; Department of Chemistry, Indonesia University of Education, Setiabudhi 229, Bandung, 40154, Indonesia; Department of Environmental Engineering & Innovation and Development Center of Sustainable Agriculture, National Chung Hsing University, 250, Kuo-Kuang Road, Taichung, Taiwan
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