Ying-Wai Cheong, Ka-Lun Wong, Boon Seng Ooi, Tau Chuan Ling, Fitri Khoerunnisa, Eng-Poh Ng
MER-type zeolite is an interesting microporous material that has been widely used in catalysis and separation. By carefully controlling the synthesis parameters, a procedure to synthesize K-MER zeolite crystals with various morphologies has been developed. The silica, water and mineralizer content in the synthesis gel, as well as crystallization time and temperature, have a profound impact on the crystallization kinetics, resulting in zeolite solids with various degrees of crystallinity, crystal sizes and shapes. K-MER zeolite crystals with nanorod, bullet-like, prismatic and wheatsheaf-like morphologies have been successfully obtained. The catalytic performances of the K-MER zeolites in cyanoethylation of methanol, under novel non-microwave instant heating, have been investigated. The zeolite in nanosize form shows the best catalytic performance (94.1% conversion, 100% selectivity) while the bullet-like zeolite gives poorest catalytic performance (44.2% conversion, 100% selectivity). © 2020 by the authors. Licensee MDPI, Basel, Switzerland.
School of Chemical Sciences, Universiti Sains Malaysia, Penang, USM 11800, Malaysia; School of Energy and Chemical Engineering, Xiamen University Malaysia, Jalan Sunsuria, Bandar Sunsuria, Sepang, 43900, Selangor, Malaysia; School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, Seri Ampangan, Nibong Tebal, 14300, Penang, Malaysia; Institute of Biological Sciences, Faculty of Science, University of Malaya, Kuala Lumpur, 50603, Malaysia; Chemistry Education Department, Universitas Pendidikan Indonesia, Jl. Setiabudhi 258, Bandung, 40514, Indonesia
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