High temperature oxidation in boiler environment of chromized steel

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F.F. Alia, T. Kurniawan, Y.P. Asmara, M.H.B. Ani, A.B.D. Nandiyanto

2017 IOP Conference Series: Materials Science and Engineering Vol. 257 Issue 1 Conference paper Cited by 21 SDG 7SDG 17 Quartile

Abstract

The demand for increasing efficiency has led to the development and construction of higher operating temperature power plant. This condition may lead to more severe thickness losses in boiler tubes due to excessive corrosion process. Hence, the research to improve the corrosion resistance of the current operated material is needed so that it can be applied for higher temperature application. In this research, the effect of chromizing process on the oxidation behaviour of T91 steel was investigated under steam condition. In order to deposit chromium, mixture of chromium (Cr) powder as master alloy, halide salt (NH4Cl) powder as activator and alumina (Al2O3) powder as inert filler were inserted into alumina retort together with the steel sample and heated inside furnace at 1050°C for ten hours under argon gas environment. Furthermore, for the oxidation process, steels were exposed at 700°C at different oxidation time (6h-24h) under steam condition. From FESEM/EDX analysis, it was found that oxidation rate of pack cemented steel was lower than the un-packed steel. These results show that Cr from chromizing process was able to become reservoir for the formation of Cr2O3 in high temperature steam oxidation, and its existence can be used for a longer oxidation time. © 2017 Published under licence by IOP Publishing Ltd.

Affiliations

Structural and Material Degradation Focus Group, Faculty of Mechanical Engineering, University Malaysia Pahang, Pekan, Pahang, 26600, Malaysia; Department of Manufacturing and Materials, Faculty of Engineering, International Islamic University Malaysia, PO Box 10, Kuala Lumpur, 50728, Malaysia; Department of Chemistry, Universitas Pendidikan Indonesia, Jl. Dr. Setiabudhi No. 229, Bandung, 40154, Indonesia

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